Laboratory for Space Sciences

Supernova Graphites

Some graphite grains found within meteorites have large isotopic anomalies indicative of a supernova (SN) origin (18O excesses combined with 28Si excesses). Microanalysis of these SN graphites (using transmission electron microscopy) revealed lots of internal titanium carbides (TiCs), with a single graphite in some cases containing hundreds of TiCs (25 - 2400 ppm). The supernova graphites formed after the TiCs and were quite good at capturing grains that formed at higher temperatures. In a single 5 micron graphite (KE3e11), hundreds of nanometer-sized TiCs were found (332 different internal grains). These internal grains have been preserved for at least 4.6 billion years in the graphite “time capsule”, and their study with TEM and NanoSIMS can reveal details about supernovae that cannot be uncovered using other methods. This is similar to doing forensic science, but here the explosions are supernovae that predate our solar system and the fingerprints left behind at the scene are characteristic isotopic signatures.

    

 

Figure: a) TEM image of SN graphite with two internal TiC (indicated by arrows) and

b) NanoSIMS isotopic image of same graphite showing 16oxygen signal

 

 

Procedure: 1) Bulk isotopic analysis of graphites to find those of supernova origin, 2) slicing of graphites with ultramicrotomy, and 3) TEM and then NanoSIMS analysis of sliced graphites

 

Continue ... internal grains within SN graphites

 

 

My brain is very large and has complex folds ... take me straight to

your paper on supernova graphites in Geochim. Cosmochim. Acta.

 

Back to the beginning.

Take a detour

How are isotopic anomalies created?

What is a transmission electron microscope (TEM)?

What is the NanoSIMS?

How does secondary ion mass spectrometry (SIMS) work?

Pictures of presolar grains.

Washington University presolar grains site

Created by: Kevin Croat